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The first scientifically useful photograph of a total solar eclipse was taken in Königsberg, Prussia, on July 28, 1851, using a silver-coated copper plate with a light-sensitive chemical layer.

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Additional insights we found via Smithsonian Magazine
The total solar eclipse was captured by Johann Julius Friedrich Berkowski using a daguerreotype plate exposed to light from a refracting telescope for 84 seconds.
By blocking out sunlight, total solar eclipses have allowed scientists to study the sun's corona, or outermost atmosphere, revealing wispy filaments and explosions of plasma from the sun's surface—coronal mass ejections—that would otherwise be too dim to see.
Before photographic techniques, humans had documented eclipses for millennia in rock carvings, cave paintings, and written documents.
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