The Montreal Protocol, established in 1987, is a landmark international treaty aimed at phasing out and banning substances that break apart ozone molecules. Composing the ozone layer, these molecules block about 98% of harmful ultraviolet radiation from the sun, but can be destroyed by atoms released by chlorofluorocarbons and other chemicals. The 1985 discovery of a growing hole in the ozone layer over Antarctica caused by CFCs prompted the agreement, which became the first treaty ratified by every UN member state in history.
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Mario Molina and F. Sherwood Rowland discovered that chlorofluorocarbons released chlorine atoms that could break down molecules making up the protective ozone layer. Despite attempts to discredit scientists and economic concerns raised by politicians, the agreement to phase out ozone-depleting substances was signed in 1987.
CFCs, which are used in old refrigerants, air conditioners, and aerosol sprays, do not react with atmospheric molecules. Once they reach the stratosphere, ultraviolet radiation breaks chlorine atoms off of them, which can each break apart more than 100,000 ozone molecules, thinning Earth's protective layer against ultraviolet radiation.
Although they make up no more than 10 out of every million molecules in the ozone layer, ozone provides outsized protection by absorbing the most energetic wavelengths of ultraviolet radiation. This absorption increases thermal energy in the stratosphere, causing temperatures there to rise with altitude.
In 1974, chemists Mario Molina and F. Sherwood Rowland showed that chlorofluorocarbons—then used as aerosol propellants, refrigerants, and industrial solvents—rise into the stratosphere and, upon being struck by ultraviolet radiation, release chlorine atoms, which break apart ozone molecules. Their work earned them the Nobel Prize in chemistry in 1995.
In the Antarctic stratosphere, polar conditions facilitate the formation of polar stratospheric clouds, which allow chlorine compounds from chlorofluorocarbons to accumulate. In 1985, British Antarctic Survey scientists detected massive springtime losses over Antarctica, as accumulated compounds destroyed significant amounts of ozone once sunlight returned.
The groundbreaking discovery of the Antarctic ozone hole in the mid-1980s marked a critical turning point, galvanizing international action to address the ozone-depleting properties of chlorofluorocarbons, which had been identified about a decade earlier. This environmental crisis was brought vividly to public attention through media pieces like this one.
Adopted in 1987 to phase out ozone-depleting substances, the agreement achieved universal ratification by all 197 UN member states, making it the first and only such international treaty in the UN's history.
Established in 1991, the Multilateral Fund for the Montreal Protocol finances developing nations' transition to cleaner technologies. It has disbursed more than $4B across more than 140 countries and was the first financial mechanism created under an international treaty.
Hydrofluorocarbons were introduced in the 1990s as ozone-safe substitutes for chlorofluorocarbons and hydrochlorofluorocarbons. However, scientists later found that they trap thousands of times more thermal energy in the atmosphere than carbon dioxide does, prompting a 2016 amendment to the Protocol to phase them out.
The ozone layer blocks almost all of the sun's harmful, including dangerous UVC rays that can damage cells by breaking chemical bonds. Without it, rates of skin cancer, crop failures, oceanic die-offs, and widespread ecosystem collapse would increase significantly, making Earth largely uninhabitable.
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