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While both butter and margarine are mixtures of tiny water droplets in a matrix of fat, butter's fatty acids are mostly saturated, while margarine's are primarily unsaturated, affecting how each melts.

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Additional insights we found via The Conversation
Butter is churned from dairy cream or milk, while margarine is made from plant fat and melts at a slightly higher temperature.
When butter is heated, its proteins and lactose combine, creating a nutty, toasty flavor—aromatics that are absent in margarine.
Butter also contains more water than margarine, resulting in more steam when heated, which is ideal for flaky pastry that requires dough to separate.
Butter gets its golden color from beta-carotene, a pigment present in grass, while producers add synthetic beta-carotene to margarine to mimic the color of butter.
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