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Although vinegar was first discovered when wine was left to sour after exposure to air, the fermentation of different base ingredients contributes to the variety of vinegars seen today.

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Additional insights we found via Compound Interest
To create vinegar, yeast first converts a raw ingredient's sugar into ethanol, followed by a second fermentation in which bacteria oxidize the ethanol into acetic acid, often facilitated by oxygen being pumped into industrial containers.
Distilled vinegar is so named because it is produced from distilled alcohol, while apple cider vinegar is made from fermented apple juice.
Balsamic vinegar is produced from the chemical conversion of sugars in cooked grapes before being aged for at least 12 years, while malt vinegar is made from unhopped beer.
Wine and rice vinegars are made from fermented wine and fermented rice, respectively, with additional chemicals, such as phenolic compounds and pyrazines, contributing to flavor and aroma.
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