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Why helium helped preserve the US' founding documents, but was later replaced

In 1951, the Charters of Freedom were stored in glass and metal cases filled with helium, which would not chemically react with the documents. After microscopic cracks were identified in the glass through which helium could leak out of and—experts feared—pollutants could infiltrate, new encasements made of aluminum, titanium, and argon replaced the old system in 2003.

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